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Презентация на тему Alkynes

BONDHydrocarbons that contain the carbon-carbon triple bond –C (triple)C- are called alkynes. Each triple bond contains one sigma (σ) and two pi (π) bonds. Because of the π bonds in their
GROUP MEMBERS:1)TOKTASSYN OLZHAS2)ZHARKYNULY YEDIL3)SATTAROV SATZHAN4)ALPYSSOV MADIALKYNES BONDHydrocarbons that contain the carbon-carbon triple bond GENERAL  FORMULAThe general formula of alkynes is CnH2n–2 where n is ALKYNYL GROUPAlkynyl groups are formed from alkynes by removing one H atom. NOMENCLATURE The naming of alkynes is similar to that of other hydrocarbons.Alkynes CYCLOALKYNES Alkynes may be cyclo compounds (cycloalkynes).The simplest stable cycloalkyne at room temperature is cyclononyne. ISOMERISM The triple bond may be in different locations in an alkyne, PHYSICAL PROPERTIESSimilar to alkanes, alkenes.1)Insoluble in water.BUT2)Soluble in organic solvents3)Density less than water CHEMICAL PROPERTIESAlkynes are unsaturated compounds and their chemical properties are similar to COMBUSTION REACTIONS ADDITION REACTIONSAddition reactions occur by breaking the π bonds of the triple ADDITION OF HYDROGENTwo hydrogen molecules are added to one triple bond using PREPERATION OF ALKYNES Alkynes can be synthesized from metallic acetlylides and alkyl halides. ACETYLENE Acetylene, the first member of the alkyne series, is one of USES OF ALKYNESHistrionicotoxin toxic alkyne present in South American frogsused to make THANK YOU FOR ATTENTION!!!
Слайды презентации

Слайд 2 BOND
Hydrocarbons that contain the carbon-carbon triple bond

BONDHydrocarbons that contain the carbon-carbon triple bond   –C (triple)C-

–C (triple)C- are called alkynes.


Each triple bond contains one sigma (σ) and two pi (π) bonds.
Because of the π bonds in their structure alkynes are unsaturated hydrocarbons.

Слайд 3 GENERAL FORMULA

The general formula of alkynes is CnH2n–2

GENERAL FORMULAThe general formula of alkynes is CnH2n–2 where n is

where n is an integer starting from 2.


Alkynes are

named by using the –yne suffix in place of the –ane suffix of alkanes.

Слайд 4 ALKYNYL GROUP
Alkynyl groups are formed from alkynes by

ALKYNYL GROUPAlkynyl groups are formed from alkynes by removing one H

removing one H atom. The most common alkynyl groups

are ethynyl, 1–propynyl, and 1–butynyl

Слайд 5 NOMENCLATURE
The naming of alkynes is similar to that

NOMENCLATURE The naming of alkynes is similar to that of other

of other hydrocarbons.
Alkynes may contain more than one triple

bond. An alkyne with two triple bonds is called an alkadiyne.

Alkenynes

Слайд 6 CYCLOALKYNES
Alkynes may be cyclo compounds (cycloalkynes).

The simplest stable

CYCLOALKYNES Alkynes may be cyclo compounds (cycloalkynes).The simplest stable cycloalkyne at room temperature is cyclononyne.

cycloalkyne at room temperature is cyclononyne.


Слайд 7 ISOMERISM
The triple bond may be in different locations

ISOMERISM The triple bond may be in different locations in an

in an alkyne, so alkynes can exhibit structural isomerism.


For the first two members of alkynes there is only one possible position for bond, so for these cases there is no isomerism.
Alkynes, alkadienes and cycloalkenes containing the same number of carbon atoms are isomers of each other.


Слайд 8 PHYSICAL PROPERTIES
Similar to alkanes, alkenes.
1)Insoluble in water.
BUT
2)Soluble in

PHYSICAL PROPERTIESSimilar to alkanes, alkenes.1)Insoluble in water.BUT2)Soluble in organic solvents3)Density less than water

organic solvents
3)Density less than water



Слайд 9 CHEMICAL PROPERTIES
Alkynes are unsaturated compounds and their chemical

CHEMICAL PROPERTIESAlkynes are unsaturated compounds and their chemical properties are similar

properties are similar to alkenes.
Alkynes undergo combustion reactions and

addition reactions, as alkenes do.
In addition, alkynes undergo substitution reactions with metals.

Слайд 10 COMBUSTION REACTIONS

COMBUSTION REACTIONS

Слайд 11 ADDITION REACTIONS

Addition reactions occur by breaking the π

ADDITION REACTIONSAddition reactions occur by breaking the π bonds of the

bonds of the triple bond. Hydrogen, halogens, hydrogen halides

and water may give addition reactions with alkynes.

Слайд 12 ADDITION OF HYDROGEN
Two hydrogen molecules are added to

ADDITION OF HYDROGENTwo hydrogen molecules are added to one triple bond

one triple bond using a nickel, platinum or palladium

catalyst. Alkenes are the intermediate products.

Слайд 13 PREPERATION OF ALKYNES
Alkynes can be synthesized from metallic

PREPERATION OF ALKYNES Alkynes can be synthesized from metallic acetlylides and alkyl halides.

acetlylides and alkyl halides.


Слайд 14 ACETYLENE
Acetylene, the first member of the alkyne series,

ACETYLENE Acetylene, the first member of the alkyne series, is one

is one of the major chemicals used in industry.

1)Very

light odor
2)Colorless
3)Soluble in water
4)Soluble in acetone
5)Boiling point -83* C
6)Can be liquified at 1*C

1)It burns with a bright flame
2)Explodes at about 15 atm pressure

Слайд 15 USES OF ALKYNES
Histrionicotoxin
toxic alkyne present in South

USES OF ALKYNESHistrionicotoxin toxic alkyne present in South American frogsused to

American frogs
used to make poison-tipped arrows
 
Ichthyothereol
highly toxic alkyne found

in the leaves of a Brazilian herb
used to kill fish

Calicheamicin and Esperamicin
extremely toxic to cells
breaks double strand of DNA
researchers are trying to use it to develop a cancer fighting drug
 
Capillin
natural plant fungicide


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