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Презентация на тему Rates of reaction

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What does rate of reaction mean?The speed of different chemical reactions varies hugely. Some reactions are very fast and others are very slow.What is the rate of these reactions?The speed of a reaction is called the
What does rate of reaction mean?The speed of different chemical reactions varies Rates of reactionWhy are some reactions faster than others? Reactions, particles and collisionsReactions take place when particles collide with a certain Changing the rate of reactionsincreased temperatureincreased concentration of dissolved reactants, and increased Slower and slower!Reactions do not proceed at a steady rate. They start Graphing rates of reaction Reactant–product mix How can rate of reaction be measured?Measuring the rate of a reaction Setting up rate experimentsWhat equipment is needed to investigate the rate of hydrogen production? hydrogen produced (cm3)time (seconds)10203040501020304050607000xyCalculating rate of reaction from graphsThe gradient of the The reactant/product mix Collisions and reactions: summary Temperature and collisionsHow does temperature affect the rate of particle collision? Effect of temperature on rateThe higher the temperature, the faster the rate Temperature and particle collisions Temperature and batteriesWhy are batteries more likely to rundown more quickly in How does temperature affect rate?The reaction between sodium thiosulfate and hydrochloric acid The effect of temperature on rate Effect of concentration on rate of reactionThe higher the concentration of a Concentration and particle collisions The effect of concentration on rate Effect of pressure on rate of reactionThe gas particles become closer together, Effect of surface area on rate of reactionAny reaction involving a solid Surface area and particle collisions Reaction between a carbonate and acidMarble chips are made of calcium carbonate. The effect of surface area on rate What are catalysts?Catalysts are substances that change the rate of a reaction Everyday catalystsNickel is a catalyst in the production of margarine (hydrogenation of Catalysts in industryCatalysts are also essential for living cells. Biological catalysts are Glossaryactivation energy – The amount of energy needed to start a reaction.catalyst Anagrams Rates of reaction: summary Multiple-choice quiz
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Слайд 3 What does rate of reaction mean?
The speed of

What does rate of reaction mean?The speed of different chemical reactions

different chemical reactions varies hugely. Some reactions are very

fast and others are very slow.

What is the rate of these reactions?

The speed of a reaction is called the rate of the reaction.

rusting

baking

explosion

slow

fast

very fast


Слайд 4 Rates of reaction
Why are some reactions faster than

Rates of reactionWhy are some reactions faster than others?

others?


Слайд 5 Reactions, particles and collisions
Reactions take place when particles

Reactions, particles and collisionsReactions take place when particles collide with a

collide with a certain amount of energy.
The minimum amount

of energy needed for the particles to react is called the activation energy, and is different for each reaction.

The rate of a reaction depends on two things:

the frequency of collisions between particles

the energy with which particles collide.

If particles collide with less energy than the activation energy, they will not react. The particles will just bounce off each other.


Слайд 6 Changing the rate of reactions
increased temperature
increased concentration of

Changing the rate of reactionsincreased temperatureincreased concentration of dissolved reactants, and

dissolved reactants, and increased pressure of gaseous reactants
increased surface

area of solid reactants

use of a catalyst.

Anything that increases the number of successful collisions between reactant particles will speed up a reaction.

What factors affect the rate of reactions?


Слайд 7 Slower and slower!
Reactions do not proceed at a

Slower and slower!Reactions do not proceed at a steady rate. They

steady rate. They start off at a certain speed,

then get slower and slower until they stop.

As the reaction progresses, the concentration of reactants decreases.

This reduces the frequency of collisions between particles and so the reaction slows down.


Слайд 8 Graphing rates of reaction

Graphing rates of reaction

Слайд 9 Reactant–product mix

Reactant–product mix

Слайд 10 How can rate of reaction be measured?
Measuring the

How can rate of reaction be measured?Measuring the rate of a

rate of a reaction means measuring the change in

the amount of a reactant or the amount of a product.

What can be measured to calculate the rate of reaction between magnesium and hydrochloric acid?

The amount of hydrochloric acid used up (cm3/min).
The amount of magnesium chloride produced (g/min).
The amount of hydrogen product (cm3/min).


Слайд 11 Setting up rate experiments
What equipment is needed to

Setting up rate experimentsWhat equipment is needed to investigate the rate of hydrogen production?

investigate the rate of hydrogen production?


Слайд 12 hydrogen produced (cm3)
time (seconds)
10
20
30
40
50
10
20
30
40
50
60
70
0
0
x
y
Calculating rate of reaction from

hydrogen produced (cm3)time (seconds)10203040501020304050607000xyCalculating rate of reaction from graphsThe gradient of

graphs
The gradient of the graph is equal to the

initial rate of reaction at that time

How can the rate of reaction be calculated from a graph?


Слайд 13 The reactant/product mix

The reactant/product mix

Слайд 14 Collisions and reactions: summary

Collisions and reactions: summary

Слайд 16 Temperature and collisions
How does temperature affect the rate

Temperature and collisionsHow does temperature affect the rate of particle collision?

of particle collision?


Слайд 17 Effect of temperature on rate
The higher the temperature,

Effect of temperature on rateThe higher the temperature, the faster the

the faster the rate of a reaction. In many

reactions, a rise in temperature of 10 °C causes the rate of reaction to approximately double.

Why does increased temperature increase the rate of reaction?

At a higher temperature, particles have more energy. This means they move faster and are more likely to collide with other particles.

When the particles collide, they do so with more energy, and so the number of successful collisions increases.


Слайд 18 Temperature and particle collisions

Temperature and particle collisions

Слайд 19 Temperature and batteries
Why are batteries more likely to

Temperature and batteriesWhy are batteries more likely to rundown more quickly

rundown more quickly in cold weather?
At low temperatures

the reaction that generates the electric current proceeds more slowly than at higher temperatures.

This means batteries are less likely to deliver enough current to meet demand.


Слайд 20 How does temperature affect rate?
The reaction between sodium

How does temperature affect rate?The reaction between sodium thiosulfate and hydrochloric

thiosulfate and hydrochloric acid produces sulfur.
Sulfur is solid and

so it turns the solution cloudy.

How can this fact be used to measure the effect of temperature on rate of reaction?



Слайд 21 The effect of temperature on rate

The effect of temperature on rate

Слайд 23 Effect of concentration on rate of reaction
The higher

Effect of concentration on rate of reactionThe higher the concentration of

the concentration of a dissolved reactant, the faster the

rate of a reaction.

Why does increased concentration increase the rate of reaction?

At a higher concentration, there are more particles in the same amount of space. This means that the particles are more likely to collide and therefore more likely to react.



Слайд 24 Concentration and particle collisions

Concentration and particle collisions

Слайд 25 The effect of concentration on rate

The effect of concentration on rate

Слайд 26 Effect of pressure on rate of reaction

The gas

Effect of pressure on rate of reactionThe gas particles become closer

particles become closer together, increasing the frequency of collisions.

This means that the particles are more likely to react.

Why does increasing the pressure of gaseous reactants increase the rate of reaction?

As the pressure increases, the space in which the gas particles are moving becomes smaller.


Слайд 28 Effect of surface area on rate of reaction
Any

Effect of surface area on rate of reactionAny reaction involving a

reaction involving a solid can only take place at

the surface of the solid.

If the solid is split into several pieces, the surface area increases. What effect will this have on rate of reaction?

The smaller the pieces, the larger the surface area. This means more collisions and a greater chance of reaction.

This means that there is an increased area for the reactant particles to collide with.




Слайд 29 Surface area and particle collisions

Surface area and particle collisions

Слайд 30
Reaction between a carbonate and acid
Marble chips are

Reaction between a carbonate and acidMarble chips are made of calcium

made of calcium carbonate. They react with hydrochloric acid

to produce carbon dioxide.

The effect of increasing surface area on the rate of reaction can be measured by comparing how quickly the mass of the reactants decreases using marble chips of different sizes.


Слайд 31 The effect of surface area on rate

The effect of surface area on rate

Слайд 32 What are catalysts?
Catalysts are substances that change the

What are catalysts?Catalysts are substances that change the rate of a

rate of a reaction without being used up in

the reaction.

Catalysts never produce more product – they just produce the same amount more quickly.

Different catalysts work in different ways, but most lower the reaction’s activation energy (Ea).


Слайд 33 Everyday catalysts
Nickel is a catalyst in the production

Everyday catalystsNickel is a catalyst in the production of margarine (hydrogenation

of margarine (hydrogenation of vegetable oils).
Many catalysts are transition

metals or their compounds. For example:

Platinum is a catalyst in the catalytic converters of car exhausts. It catalyzes the conversion of carbon monoxide and nitrogen oxide into the less polluting carbon dioxide and nitrogen.

Iron is a catalyst in the production of ammonia from nitrogen and hydrogen (the Haber process).


Слайд 34 Catalysts in industry
Catalysts are also essential for living

Catalysts in industryCatalysts are also essential for living cells. Biological catalysts

cells. Biological catalysts are special types of protein called

enzymes.

Why are catalysts so important for industry?

Products can be made more quickly, saving time and money.

Catalysts reduce the need for high temperatures, saving fuel and reducing pollution.


Слайд 36 Glossary
activation energy – The amount of energy needed

Glossaryactivation energy – The amount of energy needed to start a

to start a reaction.
catalyst – A substance that increases

the rate of a chemical reaction without being used up.
concentration – The number of molecules of a substance in a given volume.
enzyme – A biological catalyst.
rate of reaction – The change in the concentration over a certain period of time.

Слайд 37 Anagrams

Anagrams

Слайд 38 Rates of reaction: summary

Rates of reaction: summary

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